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| Aug 31 • 17:00 | Juan Ignacio Londero |  | - |  | Evgeny Donskoy | 3 | : | 0 |
| Aug 31 • 17:00 | Pablo Andújar |  | - |  | Borna Ćorić | 0 | : | 3 |
| Aug 31 • 17:00 | Dušan Lajović |  | - |  | Egor Gerasimov | 1 | : | 3 |
| Aug 31 • 17:00 | Stefano Travaglia |  | - |  | Jordan Thompson | 1 | : | 3 |
| Aug 31 • 17:00 | Diego Schwartzman |  | - |  | Cameron Norrie | 2 | : | 3 |
| Aug 31 • 17:00 | Jason Jung |  | - |  | Federico Coria | 2 | : | 2 |
| Aug 31 • 17:00 | Alejandro Davidovich Fokina |  | - |  | Dennis Novak | 3 | : | 2 |
| Aug 31 • 18:55 | Denis Shapovalov |  | - |  | Sebastian Korda | 3 | : | 1 |
| Aug 31 • 19:25 | Adrian Mannarino |  | - |  | Lorenzo Sonego | 3 | : | 1 |
| Aug 31 • 19:30 | Kevin Anderson |  | - |  | Alexander Zverev | 1 | : | 3 |
| Aug 31 • 19:45 | Pablo Carreño Busta |  | - |  | Yasutaka Uchiyama | 3 | : | 2 |
| Aug 31 • 19:45 | Jack Sock |  | - |  | Pablo Cuevas | 3 | : | 2 |
| Aug 31 • 20:00 | Mitchell Krueger |  | - |  | Pedro Sousa | 3 | : | 1 |
| Aug 31 • 20:00 | Mohamed Safwat |  | - |  | Gilles Simon | 0 | : | 3 |
| Aug 31 • 20:00 | Peter Gojowczyk |  | - |  | Hubert Hurkacz | 0 | : | 3 |
| Aug 31 • 20:20 | Stefanos Tsitsipas |  | - |  | Albert Ramos-Viñolas | 3 | : | 0 |
| Aug 31 • 20:25 | Paolo Lorenzi |  | - |  | Brandon Nakashima | 0 | : | 3 |
| Aug 31 • 21:00 | Maxime Cressy |  | - |  | Jozef Kovalík | 3 | : | 1 |
| Aug 31 • 21:15 | Dominik Koepfer |  | - |  | Taylor Harry Fritz | 1 | : | 3 |
| Aug 31 • 21:30 | Federico Gaio |  | - |  | Ričardas Berankis | 1 | : | 3 |
| Aug 31 • 21:30 | Filip Krajinović |  | - |  | Mikael Ymer | 3 | : | 0 |
| Aug 31 • 21:30 | Ulises Blanch |  | - |  | Cristian Garín | 2 | : | 3 |
| Aug 31 • 22:00 | Kyle Edmund |  | - |  | Alexander Bublik | 3 | : | 1 |
| Aug 31 • 22:00 | Thai-Son Kwiatkowski |  | - |  | Kwon Soon-woo | 1 | : | 3 |
| Aug 31 • 22:00 | Marcos Giron |  | - |  | Marc Polmans | 3 | : | 2 |
| Aug 31 • 22:00 | Attila Balazs |  | - |  | Mikhail Kukushkin | 0 | : | 3 |
| Aug 31 • 22:45 | Steve Johnson |  | - |  | John Isner | 3 | : | 2 |
| Aug 31 • 23:00 | João Sousa |  | - |  | Michael Mmoh | 1 | : | 3 |
| Aug 31 • 23:00 | Pedro Martínez |  | - |  | Jan-Lennard Struff | 0 | : | 3 |
| Aug 31 • 23:00 | Lloyd Harris |  | - |  | Marco Cecchinato | 3 | : | 0 |
| Aug 31 • 23:00 | Reilly Opelka |  | - |  | David Goffin | 1 | : | 3 |
| Sep 01 • 01:00 | Novak Djokovic |  | - |  | Damir Džumhur | 3 | : | 0 |
| Sep 01 • 17:00 | Emil Ruusuvuori |  | - |  | Aljaž Bedene | 3 | : | 2 |
| Sep 01 • 17:00 | Mackenzie McDonald |  | - |  | Casper Ruud | 2 | : | 3 |
| Sep 01 • 17:00 | Andrey Kuznetsov |  | - |  | Sam Querrey | 3 | : | 0 |
| Sep 01 • 17:00 | Jannik Sinner |  | - |  | Karen Khachanov | 2 | : | 3 |
| Sep 01 • 17:00 | Sumit Nagal |  | - |  | Bradley Klahn | 3 | : | 1 |
| Sep 01 • 18:00 | Taro Daniel |  | - |  | Gregoire Barrere | 1 | : | 3 |
| Sep 01 • 18:00 | Jérémy Chardy |  | - |  | Andrey Rublev | 0 | : | 3 |
| Sep 01 • 18:00 | Vasek Pospisil |  | - |  | Philipp Kohlschreiber | 3 | : | 0 |
| Sep 01 • 18:00 | Felix Auger Aliassime |  | - |  | Thiago Moura Monteiro | 3 | : | 1 |
| Sep 01 • 18:00 | Andy Murray |  | - |  | Yoshihito Nishioka | 3 | : | 2 |
| Sep 01 • 18:00 | Marin Čilić |  | - |  | Denis Kudla | 3 | : | 2 |
| Sep 01 • 18:00 | Norbert Gombos |  | - |  | Radu Albot | 3 | : | 0 |
| Sep 01 • 18:00 | Jaume Munar |  | - |  | Dominic Thiem | 0 | : | 2 |
| Sep 01 • 19:00 | Guido Pella |  | - |  | Jeffrey John Wolf | 1 | : | 3 |
| Sep 01 • 19:00 | Feliciano López |  | - |  | Roberto Carballés Baena | 1 | : | 3 |
| Sep 01 • 19:00 | Christopher O'Connell |  | - |  | Laslo Djere | 3 | : | 1 |
| Sep 01 • 19:00 | Roberto Bautista-Agut |  | - |  | Tennys Sandgren | 3 | : | 0 |
| Sep 01 • 19:00 | Leonardo Mayer |  | - |  | Milos Raonic | 0 | : | 3 |
| Sep 01 • 19:00 | Corentin Moutet |  | - |  | Jiří Veselý | 3 | : | 0 |
| Sep 01 • 19:00 | Thiago Seyboth Wild |  | - |  | Daniel Evans | 0 | : | 3 |
| Sep 01 • 20:00 | Salvatore Caruso |  | - |  | James Duckworth | 3 | : | 1 |
| Sep 01 • 20:00 | Márton Fucsovics |  | - |  | Hugo Dellien | 3 | : | 0 |
| Sep 01 • 20:00 | Gianluca Mager |  | - |  | Miomir Kecmanovic | 2 | : | 3 |
| Sep 01 • 20:00 | Alex De Minaur |  | - |  | Andrej Martin | 3 | : | 0 |
| Sep 01 • 20:00 | Ivo Karlović |  | - |  | Richard Gasquet | 0 | : | 3 |
| Sep 01 • 21:00 | Matteo Berrettini |  | - |  | Go Soeda | 3 | : | 0 |
| Sep 01 • 21:00 | Yuichi Sugita |  | - |  | Ugo Humbert | 0 | : | 3 |
| Sep 01 • 21:00 | Frances Tiafoe |  | - |  | Andreas Seppi | 3 | : | 1 |
| Sep 01 • 21:00 | John Millman |  | - |  | Nikoloz Basilashvili | 3 | : | 0 |
| Sep 02 • 00:00 | Grigor Dimitrov |  | - |  | Tommy Paul | 3 | : | 0 |
| Sep 02 • 00:45 | Ernesto Escobedo |  | - |  | Kamil Majchrzak | 0 | : | 0 |
| Sep 02 • 02:00 | Federico Delbonis |  | - |  | Daniil Medvedev | 0 | : | 3 |
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| Sep 02 • 17:00 | Filip Krajinović |  | - |  | Marcos Giron | 3 | : | 0 |
| Sep 02 • 18:30 | Lloyd Harris |  | - |  | David Goffin | 1 | : | 3 |
| Sep 02 • 18:30 | Egor Gerasimov |  | - |  | Jordan Thompson | 1 | : | 3 |
| Sep 02 • 18:30 | Mikhail Kukushkin |  | - |  | Cristian Garín | 3 | : | 2 |
| Sep 02 • 18:30 | Alejandro Davidovich Fokina |  | - |  | Hubert Hurkacz | 3 | : | 1 |
| Sep 02 • 18:30 | Brandon Nakashima |  | - |  | Alexander Zverev | 1 | : | 3 |
| Sep 02 • 19:40 | Novak Djokovic |  | - |  | Kyle Edmund | 3 | : | 1 |
| Sep 02 • 20:15 | Michael Mmoh |  | - |  | Jan-Lennard Struff | 0 | : | 3 |
| Sep 02 • 20:15 | Adrian Mannarino |  | - |  | Jack Sock | 3 | : | 0 |
| Sep 02 • 21:20 | Cameron Norrie |  | - |  | Federico Coria | 3 | : | 0 |
| Sep 02 • 21:45 | Juan Ignacio Londero |  | - |  | Borna Ćorić | 2 | : | 3 |
| Sep 02 • 22:15 | Pablo Carreño Busta |  | - |  | Mitchell Krueger | 3 | : | 0 |
| Sep 02 • 22:15 | Gilles Simon |  | - |  | Taylor Harry Fritz | 0 | : | 3 |
| Sep 02 • 23:40 | Ričardas Berankis |  | - |  | Steve Johnson | 3 | : | 1 |
| Sep 03 • 00:00 | Denis Shapovalov |  | - |  | Kwon Soon-woo | 3 | : | 1 |
| Sep 03 • 02:30 | Stefanos Tsitsipas |  | - |  | Maxime Cressy | 3 | : | 0 |
| Sep 03 • 17:00 | Roberto Bautista-Agut |  | - |  | Miomir Kecmanovic | 3 | : | 1 |
| Sep 03 • 17:00 | Alex De Minaur |  | - |  | Richard Gasquet | 3 | : | 1 |
| Sep 03 • 17:00 | Andrey Kuznetsov |  | - |  | Karen Khachanov | 0 | : | 3 |
| Sep 03 • 18:30 | Marin Čilić |  | - |  | Norbert Gombos | 3 | : | 1 |
| Sep 03 • 18:50 | Gregoire Barrere |  | - |  | Andrey Rublev | 0 | : | 3 |
| Sep 03 • 18:55 | Ernesto Escobedo |  | - |  | Salvatore Caruso | 1 | : | 3 |
| Sep 03 • 19:05 | Emil Ruusuvuori |  | - |  | Casper Ruud | 0 | : | 2 |
| Sep 03 • 19:25 | Vasek Pospisil |  | - |  | Milos Raonic | 3 | : | 1 |
| Sep 03 • 19:55 | Sumit Nagal |  | - |  | Dominic Thiem | 0 | : | 3 |
| Sep 03 • 20:00 | Jeffrey John Wolf |  | - |  | Roberto Carballés Baena | 3 | : | 0 |
| Sep 03 • 20:10 | Grigor Dimitrov |  | - |  | Márton Fucsovics | 2 | : | 3 |
| Sep 03 • 20:30 | Frances Tiafoe |  | - |  | John Millman | 3 | : | 2 |
| Sep 03 • 20:55 | Matteo Berrettini |  | - |  | Ugo Humbert | 3 | : | 0 |
| Sep 03 • 21:05 | Corentin Moutet |  | - |  | Daniel Evans | 3 | : | 1 |
| Sep 04 • 00:00 | Christopher O'Connell |  | - |  | Daniil Medvedev | 0 | : | 3 |
| Sep 04 • 02:30 | Felix Auger Aliassime |  | - |  | Andy Murray | 3 | : | 0 |
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| Sep 04 • 17:00 | Cameron Norrie |  | - |  | Alejandro Davidovich Fokina | 1 | : | 3 |
| Sep 04 • 18:30 | Filip Krajinović |  | - |  | David Goffin | 0 | : | 3 |
| Sep 04 • 19:30 | Denis Shapovalov |  | - |  | Taylor Harry Fritz | 3 | : | 2 |
| Sep 04 • 20:00 | Pablo Carreño Busta |  | - |  | Ričardas Berankis | 3 | : | 0 |
| Sep 04 • 20:00 | Adrian Mannarino |  | - |  | Alexander Zverev | 1 | : | 3 |
| Sep 04 • 20:30 | Jordan Thompson |  | - |  | Mikhail Kukushkin | 3 | : | 0 |
| Sep 04 • 22:00 | Stefanos Tsitsipas |  | - |  | Borna Ćorić | 2 | : | 3 |
| Sep 05 • 01:00 | Novak Djokovic |  | - |  | Jan-Lennard Struff | 3 | : | 0 |
| Sep 05 • 17:00 | Salvatore Caruso |  | - |  | Andrey Rublev | 0 | : | 3 |
| Sep 05 • 18:00 | Jeffrey John Wolf |  | - |  | Daniil Medvedev | 0 | : | 3 |
| Sep 05 • 18:30 | Matteo Berrettini |  | - |  | Casper Ruud | 3 | : | 0 |
| Sep 05 • 18:30 | Roberto Bautista-Agut |  | - |  | Vasek Pospisil | 2 | : | 3 |
| Sep 05 • 18:50 | Alex De Minaur |  | - |  | Karen Khachanov | 3 | : | 2 |
| Sep 05 • 21:45 | Márton Fucsovics |  | - |  | Frances Tiafoe | 0 | : | 3 |
| Sep 05 • 22:00 | Felix Auger Aliassime |  | - |  | Corentin Moutet | 3 | : | 0 |
| Sep 06 • 02:30 | Marin Čilić |  | - |  | Dominic Thiem | 1 | : | 3 |
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| Sep 06 • 18:30 | Alejandro Davidovich Fokina |  | - |  | Alexander Zverev | 0 | : | 3 |
| Sep 06 • 20:00 | Novak Djokovic |  | - |  | Pablo Carreño Busta | 0 | : | 0 |
| Sep 06 • 23:35 | Borna Ćorić |  | - |  | Jordan Thompson | 3 | : | 0 |
| Sep 07 • 01:00 | Denis Shapovalov |  | - |  | David Goffin | 3 | : | 1 |
| Sep 07 • 17:00 | Vasek Pospisil |  | - |  | Alex De Minaur | 0 | : | 3 |
| Sep 07 • 20:00 | Felix Auger Aliassime |  | - |  | Dominic Thiem | 0 | : | 3 |
| Sep 07 • 20:30 | Matteo Berrettini |  | - |  | Andrey Rublev | 1 | : | 3 |
| Sep 08 • 01:00 | Frances Tiafoe |  | - |  | Daniil Medvedev | 0 | : | 3 |
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| Sep 08 • 19:30 | Borna Ćorić |  | - |  | Alexander Zverev | 1 | : | 3 |
| Sep 09 • 02:30 | Pablo Carreño Busta |  | - |  | Denis Shapovalov | 3 | : | 2 |
| Sep 09 • 19:30 | Andrey Rublev |  | - |  | Daniil Medvedev | 0 | : | 3 |
| Sep 10 • 02:30 | Alex De Minaur |  | - |  | Dominic Thiem | 0 | : | 3 |
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| Sep 11 • 22:00 | Pablo Carreño Busta |  | - |  | Alexander Zverev | 2 | : | 3 |
| Sep 12 • 00:00 | Daniil Medvedev |  | - |  | Dominic Thiem | 0 | : | 3 |
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| Sep 13 • 22:00 | Alexander Zverev |  | - |  | Dominic Thiem | 2 | : | 3 |
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