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| Aug 31 • 17:00 | Juan Ignacio Londero |  | - |  | Evgeny Donskoy | 3 | : | 0 |
| Aug 31 • 17:00 | Pablo Andújar |  | - |  | Borna Ćorić | 0 | : | 3 |
| Aug 31 • 17:00 | Dušan Lajović |  | - |  | Egor Gerasimov | 1 | : | 3 |
| Aug 31 • 17:00 | Stefano Travaglia |  | - |  | Jordan Thompson | 1 | : | 3 |
| Aug 31 • 17:00 | Diego Schwartzman | | - |  | Cameron Norrie | 2 | : | 3 |
| Aug 31 • 17:00 | Jason Jung |  | - | | Federico Coria | 2 | : | 2 |
| Aug 31 • 17:00 | Alejandro Davidovich Fokina | | - |  | Dennis Novak | 3 | : | 2 |
| Aug 31 • 18:55 | Denis Shapovalov |  | - |  | Sebastian Korda | 3 | : | 1 |
| Aug 31 • 19:25 | Adrian Mannarino |  | - | | Lorenzo Sonego | 3 | : | 1 |
| Aug 31 • 19:30 | Kevin Anderson |  | - |  | Alexander Zverev | 1 | : | 3 |
| Aug 31 • 19:45 | Pablo Carreño Busta | | - |  | Yasutaka Uchiyama | 3 | : | 2 |
| Aug 31 • 19:45 | Jack Sock | | - |  | Pablo Cuevas | 3 | : | 2 |
| Aug 31 • 20:00 | Mitchell Krueger | | - |  | Pedro Sousa | 3 | : | 1 |
| Aug 31 • 20:00 | Mohamed Safwat |  | - | | Gilles Simon | 0 | : | 3 |
| Aug 31 • 20:00 | Peter Gojowczyk | | - |  | Hubert Hurkacz | 0 | : | 3 |
| Aug 31 • 20:20 | Stefanos Tsitsipas |  | - | | Albert Ramos-Viñolas | 3 | : | 0 |
| Aug 31 • 20:25 | Paolo Lorenzi | | - | | Brandon Nakashima | 0 | : | 3 |
| Aug 31 • 21:00 | Maxime Cressy | | - |  | Jozef Kovalík | 3 | : | 1 |
| Aug 31 • 21:15 | Dominik Koepfer | | - | | Taylor Harry Fritz | 1 | : | 3 |
| Aug 31 • 21:30 | Federico Gaio | | - |  | Ričardas Berankis | 1 | : | 3 |
| Aug 31 • 21:30 | Filip Krajinović | | - |  | Mikael Ymer | 3 | : | 0 |
| Aug 31 • 21:30 | Ulises Blanch | | - |  | Cristian Garín | 2 | : | 3 |
| Aug 31 • 22:00 | Kyle Edmund | | - |  | Alexander Bublik | 3 | : | 1 |
| Aug 31 • 22:00 | Thai-Son Kwiatkowski | | - |  | Kwon Soon-woo | 1 | : | 3 |
| Aug 31 • 22:00 | Marcos Giron | | - | | Marc Polmans | 3 | : | 2 |
| Aug 31 • 22:00 | Attila Balazs |  | - | | Mikhail Kukushkin | 0 | : | 3 |
| Aug 31 • 22:45 | Steve Johnson | | - | | John Isner | 3 | : | 2 |
| Aug 31 • 23:00 | João Sousa | | - | | Michael Mmoh | 1 | : | 3 |
| Aug 31 • 23:00 | Pedro Martínez | | - | | Jan-Lennard Struff | 0 | : | 3 |
| Aug 31 • 23:00 | Lloyd Harris | | - | | Marco Cecchinato | 3 | : | 0 |
| Aug 31 • 23:00 | Reilly Opelka | | - |  | David Goffin | 1 | : | 3 |
| Sep 01 • 01:00 | Novak Djokovic | | - |  | Damir Džumhur | 3 | : | 0 |
| Sep 01 • 17:00 | Emil Ruusuvuori |  | - |  | Aljaž Bedene | 3 | : | 2 |
| Sep 01 • 17:00 | Mackenzie McDonald | | - |  | Casper Ruud | 2 | : | 3 |
| Sep 01 • 17:00 | Andrey Kuznetsov | | - | | Sam Querrey | 3 | : | 0 |
| Sep 01 • 17:00 | Jannik Sinner | | - | | Karen Khachanov | 2 | : | 3 |
| Sep 01 • 17:00 | Sumit Nagal |  | - | | Bradley Klahn | 3 | : | 1 |
| Sep 01 • 18:00 | Taro Daniel | | - | | Gregoire Barrere | 1 | : | 3 |
| Sep 01 • 18:00 | Jérémy Chardy | | - | | Andrey Rublev | 0 | : | 3 |
| Sep 01 • 18:00 | Vasek Pospisil | | - | | Philipp Kohlschreiber | 3 | : | 0 |
| Sep 01 • 18:00 | Felix Auger Aliassime | | - |  | Thiago Moura Monteiro | 3 | : | 1 |
| Sep 01 • 18:00 | Andy Murray | | - | | Yoshihito Nishioka | 3 | : | 2 |
| Sep 01 • 18:00 | Marin Čilić | | - | | Denis Kudla | 3 | : | 2 |
| Sep 01 • 18:00 | Norbert Gombos | | - |  | Radu Albot | 3 | : | 0 |
| Sep 01 • 18:00 | Jaume Munar | | - | | Dominic Thiem | 0 | : | 2 |
| Sep 01 • 19:00 | Guido Pella | | - | | Jeffrey John Wolf | 1 | : | 3 |
| Sep 01 • 19:00 | Feliciano López | | - | | Roberto Carballés Baena | 1 | : | 3 |
| Sep 01 • 19:00 | Christopher O'Connell | | - | | Laslo Djere | 3 | : | 1 |
| Sep 01 • 19:00 | Roberto Bautista-Agut | | - | | Tennys Sandgren | 3 | : | 0 |
| Sep 01 • 19:00 | Leonardo Mayer | | - | | Milos Raonic | 0 | : | 3 |
| Sep 01 • 19:00 | Corentin Moutet | | - |  | Jiří Veselý | 3 | : | 0 |
| Sep 01 • 19:00 | Thiago Seyboth Wild | | - | | Daniel Evans | 0 | : | 3 |
| Sep 01 • 20:00 | Salvatore Caruso | | - | | James Duckworth | 3 | : | 1 |
| Sep 01 • 20:00 | Márton Fucsovics | | - |  | Hugo Dellien | 3 | : | 0 |
| Sep 01 • 20:00 | Gianluca Mager | | - | | Miomir Kecmanovic | 2 | : | 3 |
| Sep 01 • 20:00 | Alex De Minaur | | - | | Andrej Martin | 3 | : | 0 |
| Sep 01 • 20:00 | Ivo Karlović | | - | | Richard Gasquet | 0 | : | 3 |
| Sep 01 • 21:00 | Matteo Berrettini | | - | | Go Soeda | 3 | : | 0 |
| Sep 01 • 21:00 | Yuichi Sugita | | - | | Ugo Humbert | 0 | : | 3 |
| Sep 01 • 21:00 | Frances Tiafoe | | - | | Andreas Seppi | 3 | : | 1 |
| Sep 01 • 21:00 | John Millman | | - |  | Nikoloz Basilashvili | 3 | : | 0 |
| Sep 02 • 00:00 | Grigor Dimitrov |  | - | | Tommy Paul | 3 | : | 0 |
| Sep 02 • 00:45 | Ernesto Escobedo | | - | | Kamil Majchrzak | 0 | : | 0 |
| Sep 02 • 02:00 | Federico Delbonis | | - | | Daniil Medvedev | 0 | : | 3 |
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| Sep 02 • 17:00 | Filip Krajinović | | - | | Marcos Giron | 3 | : | 0 |
| Sep 02 • 18:30 | Lloyd Harris | | - | | David Goffin | 1 | : | 3 |
| Sep 02 • 18:30 | Egor Gerasimov | | - | | Jordan Thompson | 1 | : | 3 |
| Sep 02 • 18:30 | Mikhail Kukushkin | | - | | Cristian Garín | 3 | : | 2 |
| Sep 02 • 18:30 | Alejandro Davidovich Fokina | | - | | Hubert Hurkacz | 3 | : | 1 |
| Sep 02 • 18:30 | Brandon Nakashima | | - | | Alexander Zverev | 1 | : | 3 |
| Sep 02 • 19:40 | Novak Djokovic | | - | | Kyle Edmund | 3 | : | 1 |
| Sep 02 • 20:15 | Michael Mmoh | | - | | Jan-Lennard Struff | 0 | : | 3 |
| Sep 02 • 20:15 | Adrian Mannarino | | - | | Jack Sock | 3 | : | 0 |
| Sep 02 • 21:20 | Cameron Norrie | | - | | Federico Coria | 3 | : | 0 |
| Sep 02 • 21:45 | Juan Ignacio Londero | | - | | Borna Ćorić | 2 | : | 3 |
| Sep 02 • 22:15 | Pablo Carreño Busta | | - | | Mitchell Krueger | 3 | : | 0 |
| Sep 02 • 22:15 | Gilles Simon | | - | | Taylor Harry Fritz | 0 | : | 3 |
| Sep 02 • 23:40 | Ričardas Berankis | | - | | Steve Johnson | 3 | : | 1 |
| Sep 03 • 00:00 | Denis Shapovalov | | - | | Kwon Soon-woo | 3 | : | 1 |
| Sep 03 • 02:30 | Stefanos Tsitsipas | | - | | Maxime Cressy | 3 | : | 0 |
| Sep 03 • 17:00 | Roberto Bautista-Agut | | - | | Miomir Kecmanovic | 3 | : | 1 |
| Sep 03 • 17:00 | Alex De Minaur | | - | | Richard Gasquet | 3 | : | 1 |
| Sep 03 • 17:00 | Andrey Kuznetsov | | - | | Karen Khachanov | 0 | : | 3 |
| Sep 03 • 18:30 | Marin Čilić | | - | | Norbert Gombos | 3 | : | 1 |
| Sep 03 • 18:50 | Gregoire Barrere | | - | | Andrey Rublev | 0 | : | 3 |
| Sep 03 • 18:55 | Ernesto Escobedo | | - | | Salvatore Caruso | 1 | : | 3 |
| Sep 03 • 19:05 | Emil Ruusuvuori | | - | | Casper Ruud | 0 | : | 2 |
| Sep 03 • 19:25 | Vasek Pospisil | | - | | Milos Raonic | 3 | : | 1 |
| Sep 03 • 19:55 | Sumit Nagal | | - | | Dominic Thiem | 0 | : | 3 |
| Sep 03 • 20:00 | Jeffrey John Wolf | | - | | Roberto Carballés Baena | 3 | : | 0 |
| Sep 03 • 20:10 | Grigor Dimitrov | | - | | Márton Fucsovics | 2 | : | 3 |
| Sep 03 • 20:30 | Frances Tiafoe | | - | | John Millman | 3 | : | 2 |
| Sep 03 • 20:55 | Matteo Berrettini | | - | | Ugo Humbert | 3 | : | 0 |
| Sep 03 • 21:05 | Corentin Moutet | | - | | Daniel Evans | 3 | : | 1 |
| Sep 04 • 00:00 | Christopher O'Connell | | - | | Daniil Medvedev | 0 | : | 3 |
| Sep 04 • 02:30 | Felix Auger Aliassime | | - | | Andy Murray | 3 | : | 0 |
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| Sep 04 • 17:00 | Cameron Norrie | | - | | Alejandro Davidovich Fokina | 1 | : | 3 |
| Sep 04 • 18:30 | Filip Krajinović | | - | | David Goffin | 0 | : | 3 |
| Sep 04 • 19:30 | Denis Shapovalov | | - | | Taylor Harry Fritz | 3 | : | 2 |
| Sep 04 • 20:00 | Pablo Carreño Busta | | - | | Ričardas Berankis | 3 | : | 0 |
| Sep 04 • 20:00 | Adrian Mannarino | | - | | Alexander Zverev | 1 | : | 3 |
| Sep 04 • 20:30 | Jordan Thompson | | - | | Mikhail Kukushkin | 3 | : | 0 |
| Sep 04 • 22:00 | Stefanos Tsitsipas | | - | | Borna Ćorić | 2 | : | 3 |
| Sep 05 • 01:00 | Novak Djokovic | | - | | Jan-Lennard Struff | 3 | : | 0 |
| Sep 05 • 17:00 | Salvatore Caruso | | - | | Andrey Rublev | 0 | : | 3 |
| Sep 05 • 18:00 | Jeffrey John Wolf | | - | | Daniil Medvedev | 0 | : | 3 |
| Sep 05 • 18:30 | Matteo Berrettini | | - | | Casper Ruud | 3 | : | 0 |
| Sep 05 • 18:30 | Roberto Bautista-Agut | | - | | Vasek Pospisil | 2 | : | 3 |
| Sep 05 • 18:50 | Alex De Minaur | | - | | Karen Khachanov | 3 | : | 2 |
| Sep 05 • 21:45 | Márton Fucsovics | | - | | Frances Tiafoe | 0 | : | 3 |
| Sep 05 • 22:00 | Felix Auger Aliassime | | - | | Corentin Moutet | 3 | : | 0 |
| Sep 06 • 02:30 | Marin Čilić | | - | | Dominic Thiem | 1 | : | 3 |
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| Sep 06 • 18:30 | Alejandro Davidovich Fokina | | - | | Alexander Zverev | 0 | : | 3 |
| Sep 06 • 20:00 | Novak Djokovic | | - | | Pablo Carreño Busta | 0 | : | 0 |
| Sep 06 • 23:35 | Borna Ćorić | | - | | Jordan Thompson | 3 | : | 0 |
| Sep 07 • 01:00 | Denis Shapovalov | | - | | David Goffin | 3 | : | 1 |
| Sep 07 • 17:00 | Vasek Pospisil | | - | | Alex De Minaur | 0 | : | 3 |
| Sep 07 • 20:00 | Felix Auger Aliassime | | - | | Dominic Thiem | 0 | : | 3 |
| Sep 07 • 20:30 | Matteo Berrettini | | - | | Andrey Rublev | 1 | : | 3 |
| Sep 08 • 01:00 | Frances Tiafoe | | - | | Daniil Medvedev | 0 | : | 3 |
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| Sep 08 • 19:30 | Borna Ćorić | | - | | Alexander Zverev | 1 | : | 3 |
| Sep 09 • 02:30 | Pablo Carreño Busta | | - | | Denis Shapovalov | 3 | : | 2 |
| Sep 09 • 19:30 | Andrey Rublev | | - | | Daniil Medvedev | 0 | : | 3 |
| Sep 10 • 02:30 | Alex De Minaur | | - | | Dominic Thiem | 0 | : | 3 |
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| Sep 11 • 22:00 | Pablo Carreño Busta | | - | | Alexander Zverev | 2 | : | 3 |
| Sep 12 • 00:00 | Daniil Medvedev | | - | | Dominic Thiem | 0 | : | 3 |
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| Sep 13 • 22:00 | Alexander Zverev | | - | | Dominic Thiem | 2 | : | 3 |
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