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| Nov 02 • 11:00 | Filip Krajinović |  | - |  | Feliciano López | 0 | : | 2 |
| Nov 02 • 11:00 | Márton Fucsovics |  | - |  | Borna Ćorić | 0 | : | 2 |
| Nov 02 • 11:00 | Hubert Hurkacz |  | - |  | Radu Albot | 1 | : | 2 |
| Nov 02 • 12:30 | Jordan Thompson |  | - |  | Federico Delbonis | 2 | : | 0 |
| Nov 02 • 12:30 | Albert Ramos-Viñolas | | - |  | Marcos Giron | 1 | : | 2 |
| Nov 02 • 12:30 | Salvatore Caruso |  | - |  | Corentin Moutet | 1 | : | 2 |
| Nov 02 • 14:00 | Nikoloz Basilashvili |  | - |  | Jan-Lennard Struff | 0 | : | 2 |
| Nov 02 • 14:00 | Marco Cecchinato | | - |  | Norbert Gombos | 0 | : | 2 |
| Nov 02 • 14:00 | Ugo Humbert | | - |  | Casper Ruud | 2 | : | 1 |
| Nov 02 • 15:30 | Alex De Minaur | | - | | Stefano Travaglia | 2 | : | 0 |
| Nov 02 • 15:30 | Felix Auger Aliassime |  | - | | Marin Čilić | 1 | : | 2 |
| Nov 02 • 17:30 | Federico Coria | | - | | Benjamin Bonzi | 0 | : | 2 |
| Nov 02 • 18:30 | Pablo Carreño Busta | | - | | Hugo Gaston | 2 | : | 0 |
| Nov 02 • 22:20 | Alejandro Davidovich Fokina | | - |  | Karen Khachanov | 2 | : | 1 |
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| Nov 03 • 11:00 | Yoshihito Nishioka |  | - | | Pablo Andújar | 2 | : | 1 |
| Nov 03 • 11:00 | Stanislas Wawrinka |  | - |  | Daniel Evans | 2 | : | 0 |
| Nov 03 • 11:00 | Aljaž Bedene |  | - | | Milos Raonic | 0 | : | 2 |
| Nov 03 • 12:30 | Richard Gasquet | | - | | Taylor Harry Fritz | 2 | : | 1 |
| Nov 03 • 12:30 | Laslo Djere | | - |  | Kevin Anderson | 0 | : | 0 |
| Nov 03 • 12:30 | Tennys Sandgren | | - | | Pierre-Hugues Herbert | 1 | : | 2 |
| Nov 03 • 14:00 | Lorenzo Sonego | | - |  | Alexander Bublik | 2 | : | 0 |
| Nov 03 • 15:00 | Adrian Mannarino | | - | | Dušan Lajović | 2 | : | 0 |
| Nov 03 • 15:00 | Gilles Simon | | - | | Tommy Paul | 1 | : | 2 |
| Nov 03 • 17:30 | Miomir Kecmanovic | | - | | John Millman | 2 | : | 0 |
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| Nov 03 • 10:00 | Marin Čilić | | - | | Corentin Moutet | 0 | : | 0 |
| Nov 03 • 16:30 | Norbert Gombos | | - |  | David Goffin | 2 | : | 0 |
| Nov 03 • 18:45 | Ugo Humbert | | - |  | Stefanos Tsitsipas | 2 | : | 1 |
| Nov 03 • 19:00 | Pablo Carreño Busta | | - | | Jan-Lennard Struff | 2 | : | 0 |
| Nov 03 • 20:15 | Matteo Berrettini | | - | | Marcos Giron | 1 | : | 2 |
| Nov 04 • 11:00 | Benjamin Bonzi | | - | | Alejandro Davidovich Fokina | 0 | : | 2 |
| Nov 04 • 11:00 | Kevin Anderson | | - | | Daniil Medvedev | 0 | : | 0 |
| Nov 04 • 12:30 | Yoshihito Nishioka | | - | | Adrian Mannarino | 1 | : | 2 |
| Nov 04 • 12:30 | Diego Schwartzman | | - | | Richard Gasquet | 2 | : | 0 |
| Nov 04 • 14:00 | Alex De Minaur | | - | | Lorenzo Sonego | 2 | : | 0 |
| Nov 04 • 14:00 | Pierre-Hugues Herbert | | - | | Milos Raonic | 0 | : | 2 |
| Nov 04 • 15:30 | Jordan Thompson | | - | | Borna Ćorić | 2 | : | 1 |
| Nov 04 • 15:30 | Alexander Zverev | | - | | Miomir Kecmanovic | 2 | : | 0 |
| Nov 04 • 17:00 | Radu Albot | | - | | Andrey Rublev | 0 | : | 2 |
| Nov 04 • 18:30 | Rafael Nadal | | - | | Feliciano López | 2 | : | 1 |
| Nov 04 • 20:00 | Stanislas Wawrinka | | - | | Tommy Paul | 2 | : | 1 |
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| Nov 05 • 11:00 | Diego Schwartzman | | - | | Alejandro Davidovich Fokina | 2 | : | 0 |
| Nov 05 • 12:30 | Alex De Minaur | | - | | Daniil Medvedev | 1 | : | 2 |
| Nov 05 • 12:30 | Marcos Giron | | - | | Milos Raonic | 0 | : | 2 |
| Nov 05 • 14:00 | Marin Čilić | | - | | Ugo Humbert | 1 | : | 2 |
| Nov 05 • 15:30 | Rafael Nadal | | - | | Jordan Thompson | 2 | : | 0 |
| Nov 05 • 15:30 | Pablo Carreño Busta | | - | | Norbert Gombos | 2 | : | 0 |
| Nov 05 • 18:30 | Alexander Zverev | | - | | Adrian Mannarino | 2 | : | 1 |
| Nov 05 • 20:00 | Stanislas Wawrinka | | - | | Andrey Rublev | 2 | : | 1 |
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| Nov 06 • 14:00 | Diego Schwartzman | | - | | Daniil Medvedev | 0 | : | 2 |
| Nov 06 • 15:30 | Milos Raonic | | - | | Ugo Humbert | 2 | : | 1 |
| Nov 06 • 18:30 | Rafael Nadal | | - | | Pablo Carreño Busta | 2 | : | 1 |
| Nov 06 • 20:20 | Alexander Zverev | | - | | Stanislas Wawrinka | 2 | : | 0 |
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| Nov 07 • 14:00 | Daniil Medvedev | | - | | Milos Raonic | 2 | : | 0 |
| Nov 07 • 16:30 | Rafael Nadal | | - | | Alexander Zverev | 0 | : | 2 |
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| Nov 08 • 15:00 | Alexander Zverev | | - | | Daniil Medvedev | 1 | : | 2 |
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